According to 5 G Technology, 5 Gbps rate for data transfer, So the materials required for 5G is ultra low loss in the millimeter wave region. What are the measurement technique available currently? other than cavity, Hakki Coleman, SPDR etc..
The techniques do not differ much from those at microwaves: coaxial probe (for liquids), transmission line/waveguides, free-space=quasi-optics, resonant cavity in waveguide or free-space form and parallel plate waveguide. In general, quasioptics is the preferred choice at millimetre-waves. And if you need to measure something with very very low absorption, you may need to use a quasi-optical cavity (Fabry-Perot cavity).
Please look to my book "Microwave Dielectric Spectroscppy of Ferroelectrics and Related Materials" (Gordom and Breach Inc. Publ.) It is described methods of ferroelectrics invastigation in the millimeter region and above.