This is very dependent on the organism you are using. I work with a hyperthermophilic heterotrophic archaea that optimally grows at 82 degrees Celsius. It grows best on tryptone and maltose with a basic salt medium for hydrogen production. There is a great mini-review by Sudhanshu Pawar and Ed W. J. van Niel (2013) on thermophilic biohydrogen production that may be helpful. Goodluck!
Recently, I have published one paper on the optimization of dark fermentation hydrogen production, considering all possible physicochemical parameters. The optimization was performed using statistical and AI approaches.
Article Optimization of dark fermentative hydrogen production from o...