When performing hydrograph separation (EMMA method) with isotope tracers in river confluences (natural large basin), we found that the contribution of each end member sometimes exceeds the theoretical extent of (0,1). For those within this extent, seldom cases can be observed to match the result based on discharge data.
We have considered the disturbance introduced by groundwater recharge along the bank, but the sampling sites is not too far from each other for which we think the contribution can be neglected.
What are the possible controls accounting for this observation? We are waiting for the answer, thank you.