Water samples are planned to be collected in non-light transparent bottles with tight caps and we plan to preserve with hydrochloric acid and will be transported in an ice box for laboratory analysis.
2% HCl or HNO3 should be fine. It is said that we add acid to bring the pH to 2 which requires few drops of concentrated acid (HNO3 or HCl). The idea behind adding the acid is to cease microbial activities.
I totally agree with John Machell's and Manish Kumar's answers. With most water samples I used 1-2 ml HNO3 (preferred because all nitrates are highly soluble), depending on the buffer capacity of the water samples.