Photoluminescence (PL) spectra of the single crystal organic sample shows broad single peak only. Can I consider it is mixed with impurity or? Please explain? The attached file is the recorded PL for the sample.
I agree with S. Kataria. You shoul measure low temperature PL. Then you should simulate/fit experimental results using Gaussian, Lorenztian etc. function or you can plot your results log(Intensity)-energy scale. If is there any shoulder on your results, then it gives activation energy of impurity.
There is a single slop in your figure. But PL spectrums shows that spectrum is not completed, isn't it ? I understand that there is no edditional redative state. Could you send data for Gauss, Lorentz fitting ?
What is the criteria for chosen of Gaussian or Lorenztian fitting for PL because both are different distribution function? I am puzzling with this questions, people are random;y using both functions for PL fitting.