Instead of directly printing the medical grade structure, you could also make a mould/cast from a regular print using one of the many easy and cheap dental silicons (e.g. https://www.dentalsky.com/elite-hd-light-body-fast-zhermack.html) and resins (e.g. http://www.masterbond.com/tds/ep42ht-2med - I don't know if this is a good value for money one), and or epoxy (e.g. http://www.jpkummer.com/en/epo-tek-adhesives?p=epoxy), PDMS (e.g. Sylgard 184 Silicone Elastomer), and field's metal (for creating complicated hollow flexible casts). That way you can also do some post-processing on the prototype before casting the final object(s).
Depending on the type of printer you are looking at you can always use Poly-med. They provide a wide array of biodegradable polymers with different degrees of stiffness. We have used a few in our lab for different applications and they are easily printed on any extrusion-based printer.
Sorry, for the late response. We got some samples from them and made test prints for tracheal stents and cartilage boats. Unfortunately, we never got around to actually applying cells to the prints but they were successfully printed! They have many different options that are medical variants of traditional filaments, such as PLA, PCL, PETG, etc. Deepak Choudhury