Is it that in hard-rock formations, groundwater character is essentially determined by hydraulic gradient rather than chemical rock-water interaction ?
In case of hard rock formations, the ground-waters tend to have more uniform compositions because they obtain their character through mixing along fairly rapid conductive flow paths, i.e., mainly determined by the hydraulic gradient, rather than by chemical rock-water interaction.
If it is so, then, the concept of "fracture density" (number of fractures available per unit volume) would play a crucial role in deciding the resultant groundwater character?