Is "Encapsulation of Polyoxometalates in MOFs" and "composites of polyoxometalates with MOF" different or same?

29 July 2015 1 8K Report

If the pore size of MOF is smaller than the POM size then encapsulation is impossible. But is their any chance of adsorption of POM on the surface of MOF making a composite?

Imre Tóth

Sure, there is. Of course the efficiency and extent of adsorption depends strongly both on the nature of the surface and the POM. See some examples below: http://pubs.rsc.org/en/Content/ArticleLanding/2012/SC/c2sc20210g#!divAbstract ; http://www.quimica.urv.es/w3qf/superficies/poms.html ; http://www.researchgate.net/publication/229064946_Functionalization_and_post-functionalization_A_step_towards_polyoxometalate-based_materials?enrichId=rgreq-e18da8a4-1753-496a-948b-6c5b11f7000a&enrichSource=Y292ZXJQYWdlOzIyOTA2NDk0NjtBUzo5OTQ0MDk1ODM3Nzk5NEAxNDAwNzE5OTgwMzcx&el=1_x_3 ; https://books.google.hu/books?id=FUqzig2p4PAC&pg=PA268&lpg=PA268&dq=adsorption+of+polyoxometalates+in+macroporous+materials&source=bl&ots=3-KuXznqbF&sig=ll0WD_7LZ_2haaKf9RO3AY1_jUY&hl=en&sa=X&ved=0CF0Q6AEwCGoVChMIy5bZlbSKxwIVyxEsCh1T6wML#v=onepage&q=adsorption%20of%20polyoxometalates%20in%20macroporous%20materials&f=false

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