You can't connect to the Arduino via LIFA and Bluetooth at the same time using LIFA. LIFA is only designed for a single control method (LabVIEW). It would probably be possible to control it from both the computer and the smartphone but it would need to be entirely custom code (in the Arduino and in LabVIEW).
What exactly is your scenario? If you explain how you need your system to work (why do you need the PC and LabVIEW?, etc.), it will probably be easier to suggest a possible solution.