Refined oils from plant seeds are mixtures of triacylglycerols (TAGs), up to 99%, but they still contain some amount of other lipids and small molecules.
In general, edible plant oils contain 98% triglycerides, 2% phospholipids, and a variety of hydrocarbons [Article Heating effect on quality characteristics of mixed canola cooking oils
].For example, as can be seen on the photograph, these impurities lead to a formation of a middle layer when you mix various vegetable oils (corn, canola, walnut oils in this case) with water, mix them into an emulsion and then separate them into 2 phases by centrifugation.
What are the common methods to further purify plant oils into essentially pure triglyceride liquids, which would then form a plain oil/water interface?