Perhaps the maths are simple enough: 1 mole TiCl4 means ~ 190 g , so simply dissolving 19 g in 100 ml would do. The problem is, TiCl4 rapidly hydrolyzes to Ti-chloro-Oxyhydroxides and HCl, so the solution cannot be stable at all. I suppose Mahima Yadav is asking for what chemical component to add in which manner and which amount, regarding equilibrium target concentration is required for the purpose. I think such solution is virtually impossible to remain stable at ambient temperature and pressure