If it is still actual and if you are familiar with excel macros. In above link you can find excel VBA functions/subs which should perform LU decomposition and many others matrix operations in excel.
I'm working with MS Office 2010 (Windows 7) and the functions I was interested in works fine. However I have only experience with Matrix Lite package, which should work also for MACs. Functions/subs from this particular package was not tested, therefore in my VBA project I have to made in few cases some minor modifications of the source code. It seems that many functions in this package are translations from fortran code (from Press et al. Numerical Recipes 2nd ed.), so you can find useful information there.
If you have basic about Excel VBA you will manage that. I have no experience with other packages from this page, so you have to try then.