In my experiment, firstly i measured NIR luminescence for the complex at 5 K, 100 K, and 300 K without heating which revealed very weak luminescence intensity. However, upon heating the sample to below melting point at 350 K, emission intensity increased almost 10 times compared to the previous signals. It increased even more upon measuring at lower temperatures.
Thomas Mayerhöfer
The Boltzmann-distribution should do the trick, https://en.wikipedia.org/wiki/Boltzmann_distribution , and explain your findings.
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