I would like to simulate an ideal perfect magnetic conductor (PMC) in CST studio. Since CST doesn't have PMC, it only has PEC, how should I define the material's properties?
I should see concretely what you want to do. I work quite often with AMC (Artificial Magnetic Conductor), and I create structures that simulate that behavior.
In your generic case, I think you could use the boundary conditions and put the wall you want with Magnetic Wall.