Pradeesh,

I assume you are asking for the correct ratio of oxidant to monomer for chemical oxidative polymerization. To some extent, this depends on the oxidant and monomer system that you are interested in. However, for most such systems, one-electron oxidants are used and the removal of two electrons are required for each monomer-monomer couple. As such, you need at minimum two equivalents of oxidant.  However, as the growing polymer can also undergo oxidation that does not contribute to polymer growth, an excess of oxidant is typically utilized, with common ratios being 6-10 equivalents of oxidant to one equivalent of monomer.

The ratio to be taken for preparation of polymer  is  oxidant 0.005M and monomer 0.303M with reductant. Refer this paper for further information regarding preparation of polymer. Attached is the soft copy for your reference.