The molecules separation medium is associated to medium permittivity of Frenkel effect and naturally diverse environmental temperature may influence the electron transfer process in organic materials due to absorption of light.
Do you understand what have you written? Have you read any textbook on Marcus theory? " Marcus free energy ," " electron transfer state" are highly scientific terminology. The best for you would be to remove your post.
So, molecular system electron transfer state does not have any thermal effect? If so the factor Exp - {(delG+ lamda)square/ 4*lamda* KT} how it varies. Even lamda how changes due to diverse dielectrics medium?
Since energy activation is related to (del G+ lamda) and lamda = reorganization energy it self varied with separation. However, separation has lot of influence of medium dielectric property.
@ Yurii V Geletii please see below and attachment (Free Energy Contribution of the Nonequilibrium
Polarization)
https://www.youtube.com/watch?v=YFzeMMOvhl0&t=400s
Your question uses scientific terminology and looks like scientific. I have wasted much time to understand what are you asking about. You advised me to read the excellent paper, but have you read it yourself? The youtube lecture is 1 h 25 min long. I can't consider myself as an expert in Marcus theory, but I know the basics. I have never heard about " Marcus free energy ," " electron transfer state," " "medium permittivity of Frenkel effect." Have you heard about the "working term?"
I'm no longer willing to waste my time to go through your posts.
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