Diacetylenes are a conjugated system consisting of two triple bonds. The solid state polymerization of diacetylenes proceeds as 1,4-addition to the conjugated triple bonds and gives rise to polymers with a fully conjugated backbone.
Here is a reference to one of the earliest papers: http://pubs.acs.org/doi/abs/10.1021/ja00489a015
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There are some diacetylenes which undergo polymerization reaction upon exposure to UV radiation. What property of the material is responsible for their UV sensitivity?
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The shift in Raman peaks implies increase or decrease of conjugation length of polydiacetylenes?
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During radiation induced polymerization of diacetylenes will it be useful to prepare monomers in nano range to increase the chain length.
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Why?
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