So I'm trying to determine what radical this is captured with DMPO. How do I determine and calculate what radical this is? Thanks!!
In which experimental conditions did you obtain this spectrum?
It is probably the DMPO-OOH. You can check on the Bruker website https://www.bruker.com/pt/products-and-solutions/mr/epr-instruments/epr-in-life-science.html
It is possible.
The hydroperoxyl radical can only subsist at pH 4 or lower (acidic medium; the pKa is 4.4).
The spectrum do not correspond to the DMPO adducts with hydroxyl radical or its conjugate base.
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