It is well known plasma frequency is a relevant material parameter, how difficult or easy is to have a direct experimental determination of such parameter?
Your question relevant and important both. In the case of gaseous plasmas, the plasma frequency could be determined with the help of a Langmuir probe, spectroscopic techniques, etc. In contrast, for a solid, the plasma frequency could be determined empirically with the knowledge of the electronic concentration (wp^2 ~. ne).