Yes, you can do the by doing the Butler-Volmer equation solving at linear characteristic at very small over potential. Then final eqn. become to i=-Iofη. Charge transfer resistance will be -η/i
eqn.: Rct=RT/Fi0
R,T,F standard constant
i0 is the exchange current density and you can get this by doing Tafel plots analysis.
Please follow the book Electrochemical Methods by A. J. Bard for better understanding (Chapter 3)
Thank you for your reply. Yes, that's the normal way to do it. Thank you for making it clear, but the thing is that I need to polarize the surface to the large extent. At very small perturbations, the i0 is the i0 for the net reaction (anodic-cathodic), but what I need is to find the charge transfer reaction only for the anodic reaction. I mean +60 mV or higher overpotential wrt. OCP. Is there anyways (except EIS), to find the charge transfer resistance using other techniques in this high range of overpotentials?
Dear Mohiedin. You may also try to use the Butler-Volmer equation, but neglect the exchange current because you are working in an area far from equilibrium