in fact I want to know how can we find the function between total pressure and boiling temperature for the two phase flow trapped in an insulated vessel which is exposed to constant heat flux?
the only law I know is modified Rault's law(Gamma/Phi formulation of VLE) , in it the parameters xi (composition of liquid) and yi(composition of vapor) and other parameters constantly change during the rising temperature.
how can I find the relation between compositions and temperature in order to make the equation in 2 parameter P total and T boil?
it's noticeable that we have real gas and real liquid and simplifying assumption there is equilibrium between two phase during rising temprature and both phases are not binary
I will appreciate if someone explain this