I am currently working on the synthesis of diarylic sulfides with amino groups, but it has been hard obtain meta isomers. Is it possible?
Nitrobenzene should react directly with chlorosulfonic acid to give you 3-nitrobenzenesulfonyl chloride, which you can then selectively reduce with triphenylphosphine to give the desired aryl thiol.
Here are a few references:
Bioorganic & Medicinal Chemistry, 12(6), 1413-1423; 2004
Synthesis, (19), 3211-3213; 2009
For your synthesis pls check Tetrahedron Letters, 23, p. 4701, 1982
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