I need to calculate the saturated vapour pressures so I can find the relative volatilities for the shortcut method for the design of a distillation column.
Aspen doesn't have constants for the 3 constant version of the Antoine equation. The closest Aspen comes is a form called the extended Antoine equation, which has 6 coefficients if memory serves. You'd be much better off going to a handbook like Lange's Handbook of Chemistry, which has a rather extensive listing of Antoine coefficients.
Or you could try here
https://app.knovel.com/web/toc.v/cid:kpYHACVPEH
If you add the Aspen Properties add-in to Excel, you can call its vapor pressure function for various temperatures and then regress the Antoine coefficients yourself...seems like a lot of work when other sources are easily available.