How can I find out the EPR parameters for a copper complex?

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Abdul Hameed

which parameter (magnetic parameter like susceptibility etc etc) you want to calculate?

Kanniah RajKumar

Suggest me for following Parameter : ∆H, R, µeff .

In my metal complexes, alkylation of ligand is a vital role.

1. How can i expose my alkylation in epr parameters or which parameters ?

Kindly reply me

Bojidarka B. Ivanova

Mr. Kumar,

Please find as attachment the equs for (mu)eff for Td and Oh complexes of Cu(II), refs and the dependencies. The enthalpy you may find using the common relationship that the free Gibbs energy has been given by -SdT-MdB (M-integral of the magnetisation towards the whole sample, B-external magnetic field). You may find zhis relationship anywhere. But what is R - universal gas constant? You would like to confirm the well known value using the relationship for the magnetic heat capacity!?