Are you going to measure at different depths of soil profile? Collect undisturbed soil core samples and make soil-solution mixture, and use bromide-specific electrode for Br- measurement. Read this article: http://onlinelibrary.wiley.com/doi/10.1002/hyp.3360010406/abstract
Or, Ion chromatography gives more precision results.
Yes, unfortunately you need to buy this article. Alternatively you can request them for a copy of MS. Follow this link: Article Bromide as a conservative tracer for soil‐water studies
I've found another article in the RG as follows. They published full text.
Article Winter Wheat Starter Nitrogen Management: A Preplant Soil Ni...