"Region of the electromagnetic spectrum extending from about 400 nm to 760 nm. This is the wavelength region to which the human eye is sensitive. There are no precise limits for the spectral range of visible radiation since they depend upon the amount of radiant power reaching the retina and on the responsivity of the observe"
TiO2 does not absorb light at >400 nm. You need to provide more information to answer your question.
The photochemical reaction proceeding on a TiO2 surface when irradiated with UV light (400 nm) by several approaches which including TiO2 modification :
Comparative study on UV and visible light sensitive bare and doped titanium dioxide photocatalysts for the decomposition of environmental pollutants in water
Article in Applied Catalysis A General 417-418:26-36 · December 2011
DOI: 10.1016/j.apcata.2011.12.018
Peroxo group enhanced nanorutile as visible light active photocatalyst