In case that the gold electrode builds a schottky contact, reducing its thickness will degrade such Schottky contact and if nearly removed, there will be no rectifying contact and consequently no pv affect observed.
If you displayed the i-v curve with different gold thickness, and the layer structure of your perovskite cell, one may give more elaborate answer.
In case that the gold electrode builds a schottky contact, reducing its thickness will degrade such Schottky contact and if nearly removed, there will be no rectifying contact and consequently no pv affect observed.
If you displayed the i-v curve with different gold thickness, and the layer structure of your perovskite cell, one may give more elaborate answer.
Concerning the optimum thickness, it is so that as the thickness increases the metal semicondcutor contact works better since the whole surface will be covered of the metal atoms. In addition the resistance of the metal layer will be smaller reducing the total series resistance of the solar cells and thereby the power loss will decrease and the fill factor increase enhancing the operation of the solar cell. The maximum thickness is limited by the allowed series resistance of this metal layer such that its resistance must be much smaller than the semicondcutor layer resistance.