Angell, James Joshua MS Thesis (2011) presented to The Department of Materials Engineering, California Polytechnic State Uinverstiy. (Google search the thesis title SYNTHESIS AND CHARACTERIZATION OF
Here's a recent paper on making Si-gold Core-shell particles that may help you: http://pubs.rsc.org/en/content/articlelanding/2013/nr/c3nr05960j#!divAbstract
Using this method they coated Si quantum dots with gold nanoparticles to make semiconductor-metal core-shell particles.