I know that you can prepare a SBA type materials with large pores by using during the synthesis bulky or larger organic molecules with the tensioactive agent.
At my knowledge, one times sizes of pores are defined after preparation, any molecules organic or non can modify the sizes of rigid pores!
You can read the paper Langmuir, 2007, 23 (13), pp 7247–7254
Article Pore Size Tailoring in Large-Pore SBA-15 Silica Synthesized ...