I'm looking for the software to calculate Fe2+ Fe3+ for tourmalines. But I cant' fin reliable link for WinTcac, also looking for something similar
It doesn't sound like you are asking the correct question. Tourmalines vary significantly in the iron ion ratios. Software isn't going to find that for you.
https://www.researchgate.net/publication/326739441_Determination_of_ferrous-ferric_iron_contents_in_tourmaline_using_synchrotron-based_XANES
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