Acrylic acids and acrylamides are commonly soluble in water, nevertheless their polymerization by free radicals in bulk are normally exothermic. You can use acrylates with a long aliphatic chain but take in account that the longer the chain the lower the solubility in water;so you need to find a good balance in those properties.
I may also add methacrylic acid H2C=C(CH3)-COOH. This is a water-soluble monomer. But take care since this monomer may undergo fast exothermic "popcorn" polymerization. You just place an ice- water bath nearby in the hood & once you sense, by your hands, that the r.b.flask is warming up, surround the flask with the bath immediately.