The Centre for Renewable Energy Systems Technology (CREST) at the University of Loughborough measures such data. I am not sure if they make it available, but it could be worth asking them. http://www.lboro.ac.uk/research/crest/research/appliedphotovoltaics/solar-resource--pv-performance-monitoring.html
Paul, there are some data on the irradiation in the last PV Report http://www.ren21.net/status-of-renewables/global-status-report/, maybe you could find something interesting for you.