ORP and pH are linearly related, but the slope and y-intercept depends on redox reactions. If you know your reactions, then use Nernst equation (http://en.wikipedia.org/wiki/Reduction_potential). If you are dealing with environmental sample with no specific redox reactions, then you have to measure it experimentally. Example: http://onlinelibrary.wiley.com/doi/10.1111/j.1365-2621.2002.tb08689.x/abstract