Zero valent iron means unoxidized iron, i.e. it is the same, opposite to iron oxide particles. See no use for phosphates, ammonia and nitrates. Opposite iron oxides will bind phosphates.
According to my literature survey, based on characteristics of Iron Nano particles there is a chance to treat/remove phosphate and nitrates form water.
I want to know that is it possible to use both of them or not, and as you said, there's no different between 'Zero-valent Iron Nano Particles' and 'Iron Nano Particles'.
Could you please tell me what kind of elements or substances (both solid or liquid) we can use to remove/decrease the amount of pollutants (especially Nitrogen and Phosphorus) from water?
to remove nitrogen and phosphorus from wastewater most efficient are options to allow for reuse as fertilizer. One promising alternative is struvite precipitation under controlled conditions. I would recommend you to read the different issues of the Scope newsletter.
Removal through iron phosphate results in poorly available phosphate.