I tried to mechanically disperse the hydrophobic fumed silica into the epoxy resin, but it has no significant effect on the hydrophobicity of epoxy resin.
Silanation with trialkoxy alkylsilanes is common useful method :
1) http://file.scirp.org/pdf/AMPC_2015021610385335.pdf
2) http://www.dowcorning.com/content/publishedlit/26-1402-01.pdf
Hexamethyldisilazane is also useful reagent for simple silica hydrophobization
http://www.google.com/patents/US4719243
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