You have to mechanically check under loose bark, in dead wood or to search green plants for the larvae. It depends on which groups of the Buprestidae are you speaking about.
There is no a single method to search for buprestid larvae. Every plant and buprestid life-form as well as the species and systematic group has its own peculiarities (see Bily, 2003). Julodine larvae live in the soil near the roots of different plants (for example, Alhagi) and pupate within soil cases, however there is no way to spot them in the soil without digging. Leaf-mining larvae (only Trachys and ?Habroloma in Iraq) can be found within the leaf mines on different plants. Xylophagous larvae can be found under the bark or within a sapwood of usually sick or dying (but sometimes apparently healthy) trees and bushes; sometimes infested area marked with exit holes on the surface or gall-shaped swelling (usually on the live branches or roots, see Korotyaev et al., 2005). Rhizophagous larvae can be found within the roots based on the same symptoms but many of them also live in the roots of herbaceous plants (some Acmaeoderella, Sphenoptera). Larvae of stem-boring Aphanisticini develop within the stems of herbaceous plants, their presence can be indicated by partly drying stems or usually black eggs on the stem surface. At last, Cyphosoma larvae develop inside root tubers of Bolboschoenus maritimus (L.) Palla (Cyperaceae) (see https://www.zin.ru/animalia/coleoptera/rus/cypeupbi.htm or https://www.researchgate.net/publication/275823293_Volkovitsh_BA_Korotyaev_2007_Biology_of_larva_of_Cyphosoma_euphraticum_Buprestidae_in_Russian on this site).
Good luck!!!
Literature
Bílý S. 2002: Summary of the bionomy of the Buprestid beetles of Central Europe (Coleoptera: Buprestidae). Acta Entomologica Musei Nationalis Pragae, Supplementum 10: 1-104.
Korotyaev B.A., Konstantinov A.S., Lingafelter S.W., Mandelshtam M.Y., Volkovitsh M.G. 2005. Gall-inducing Coleoptera. Pp. 239-271. In: Raman A., Schaefer C.W., Withers T.M. (Eds.). Biology, ecology, and evolution of gall-inducing arthropods. Vol. 1. Science Publishers, Inc., Enfield (NH), USA, Plymouth, UK. 817 pp.
Data Volkovitsh, B.A. Korotyaev. 2007. Biology of larva of Cyphos...
Most Buprestidae species are host specific, so it depends on which species you want to collect, for instance for the large Euchroma gigantea larvae you must search on Ceiba pentandra trees, which is the main host plant in the Neotropical region.
Buprestidae will tend to infest certain species of trees. The species vary from one region to another. Look for freshly infested trees. this you can check for exit holes on the stems or branches. I have managed to recover a number of Buprestid species from Acacia species which have been cut or dying. They rarely attack fresh trees. They tend to be just below the bark of the tree. Many don't survive once exposed or removed from the stems.