You probably mean condensed water-methanol mixture during distillation of such a mixture. Perry's chemical engineers handbook contains extensive compilation of density/concentration data for water-methanol system. You just need to measure the density of the mixture and then look up in the table for the concentration of methanol.
Thanks a lot for this question. Thanks so much for all colleagues for their contribution. I can use the the density of mixture water + methanol and comare it with the density of pure water and the density of pure methanol at the same temperature.