Strong acid can cleave the complexes e.g. HCl /H20 in diglyme. see below. Sodium methoxide in diglyme liberates an Amine from an Amine Borane compelx.

Acidic hydrolysis leads to an Amine hydrochloride.

see

Brown, Murray, Inorg. Chem. 1984, pp 2746-2753

Thank you Matthew, for the useful information

ok.

You may find in the followim=ng links

www.ncbi.nlm.nih.gov/pubmed/11428040

pubs.acs.org/doi/pdfplus/10.1021/jo982290w

https://h2tools.org/sites/default/files/bp.../nbh_h2_storage_survey.pdf

thank you Jagadeesh, for your valuable references

We were used to add HCl/MeOH and heat until dryness, maybe repeating the procedure 2-3 times. Our complex was indeed very strong. 

Dear

Sudhakar Yellapu

Using of HCl- H2O(1:1) with stirring for 1-2 hrs.,filtration, washing with water is very useful in such case.

Good luck

Thank you Ercolani and Talaat. I'm trying the same and once I get the result I'll let you know the strongnes of the borane-amine bond