I try to understand how salinity builds up in pots (with probably mostly peat moss but could also be some of the other common ingredients like bark, sand, vermikulite), both in general and specifically for ammonium.
For a 10L pot with such a soil mix, CEC might be 15meq/100cm3 which means it can hold roughly 15*39 mg per 0.1L which means 59g of K+ or 27g of NH4+ (simplified analysis) which sounds like more than I would expect but I can't find any error in my calculation.
A typical amount of N in watering can (when liquid fert and used every watering) is 50mg of N per L of water (which is 50ppm). Assume the 10L soil can hold 2L of water, that is 100mg of N. I look up in a table that 50ppm of N in water gives the water a salinity level of 0,2 mS/cm. Let's assume the plant consumes half of the applied fert. Assuming we start from zero (no fert and no water in soil), does that mean that at 2nd watering soil has 100+50mg of N, and after x waterings 100+50*x mg? And assuming this goes on without leaching, and assuming all N is NH4+, and no bacteria present to convert NH4+ to NO3- (because too cold or no oxygen), after 540 waterings I would reach the ceiling of the CEC at 27g and then have 27000 ppm and salinity of 108 mS/cm? Which is beyond insanely high but I still can't see any error in my calculations (and I realize situation is unrealistic).
Finally my most important question: I wonder to what extent CEC applies to NH4+ and K+? Because many say that ammonium is virtually unleachable if CEC is high (but those guys usually discuss clay), while at the same time Bunt in his invaluable book from 1988 says "The CEC of peat moss and bark are such that divalent cations (Ca2+ and Mg2+) are adsorbed but most monovalents cations (NH4+, K+, Na+) remain water soluble." meaning CEC does not apply to NH4+ and K+, that they are fully mobile and leach easily?
(Reasons for wanting to understand this is understanding salinity buildup, best action if have overfertilized, and scenario that leads to ammonium toxicity, just to mention a few top reasons.)
I have read a bunch of academic papers and books but get no definite answer, I can't even find a book that really delves into this.