silver nano particles can be synthesized from various plant extract
B R Siddharth Your questions are very similar...
https://www.researchgate.net/post/What_is_the_mechanism_of_production_of_silver_nano_particls_by_plant_extract_what_is_the_role_played_by_plant_extracts
The nature of the reducing agent is key. One can get pure inorganic reducing agents. It's hard to get a 99.99999% pure 'plant extract'. Too much variation in living things...
Alan has rightly referred you the very precise article.
Recomend
Synthesis and properties of silver nanoparticles: advances and prospects
Krutyakov,Yu A et al.Russian Chemical Reviews(2008),77(3):233
http://dx.doi.org/10.1070/RC2008v077n03ABEH003751
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