The attached XRD analyse shows the different phases, as can be seen there are many phases of Calcite mentioned by C, my question is, why there are many 2-teta for a same Calcite phase? are they different from each other??
You have different types of calcite from low- to high-Mg calcite and from low to high Fe calcite. The host is still calcite and neither magnesite nor siderite.
You can distinguish them and also quantify these species.