22 January 2019 11 251 Report

The universal/molar/ideal gas constant R is given by

R=PV/nT; this however, on an average, is considered true for gases (H2, O2, N2 are excluded). Involving R in chemical expressions dealing with gases is understandable; but could it's inclusion in the chemical equations, primarily evolved for the gases and later being used for liquids as well be justified? To be more specific, I am talking about the Dubinin isotherms which are also being used for modelling the adsorption of adsorbates present in a liquid, uses the term RT for determining the adsorption energy. Is it justified? Please enlighten me; I am eager to hear from you.

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