Hello everyone:
I need some help, I got confused about those kind of methods: potentiometric and electrometric method, is it a different property measure? Please, send me some link (PDF or really good book).
Thank you a lot.
Have a nice day ;)
Dear Tatiana,
Electro analytical (electrometric) methods are a class of techniques in analytical chemistry which study an analyte by measuring the potential and/or current (amperes) in an electrochemical cell containing the analyte. These methods can be broken down into several categories depending on which aspects of the cell are controlled and which are measured. The three main categories are potentiometry (the difference in electrode potentials is measured), coulometry (the cell's current is measured over time), and voltammetry (the cell's current is measured while actively altering the cell's potential).
Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. One electrode is called the reference electrode and has a constant potential, while the other one is an indicator electrode whose potential changes with the composition of the sample. Therefore, the difference of potential between the two electrodes gives an assessment of the composition of the sample. Potentiometry usually uses indicator electrodes made selectively sensitive to the ion of interest, such as fluoride in fluoride selective electrodes, so that the potential solely depends on the activity of this ion of interest. The most common potentiometric electrode is the glass-membrane electrode used in a pH meter.
Skoog, Douglas A.; Donald M. West; F. James Holler (1995-08-25). Fundamentals of Analytical Chemistry (7th ed.). Harcourt Brace College Publishers. ISBN 0-03-005938-0.
Kissinger, Peter; William R. Heineman (1996-01-23). Laboratory Techniques in Electroanalytical Chemistry, Second Edition, Revised and Expanded (2 ed.). CRC. ISBN 0-8247-9445-1.
Bard, Allen J.; Larry R. Faulkner (2000-12-18). Electrochemical Methods: Fundamentals and Applications (2 ed.). Wiley. ISBN 0-471-04372-9.
Zoski, Cynthia G. (2007-02-07). Handbook of Electrochemistry. Elsevier Science. ISBN 0-444-51958-0.
http://pubs.rsc.org/en/content/articlelanding/1947/an/an9477200094#!divAbstract
https://en.wikipedia.org/wiki/Electroanalytical_method
http://chemwiki.ucdavis.edu/Core/Analytical_Chemistry/Analytical_Chemistry_2.0/11_Electrochemical_Methods/11.2%3A_Potentiometric_Methods
Hoping this will be helpful,
Rafik
Dear Tatiana,
Electro analytical (electrometric) methods are a class of techniques in analytical chemistry which study an analyte by measuring the potential and/or current (amperes) in an electrochemical cell containing the analyte. These methods can be broken down into several categories depending on which aspects of the cell are controlled and which are measured. The three main categories are potentiometry (the difference in electrode potentials is measured), coulometry (the cell's current is measured over time), and voltammetry (the cell's current is measured while actively altering the cell's potential).
Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. One electrode is called the reference electrode and has a constant potential, while the other one is an indicator electrode whose potential changes with the composition of the sample. Therefore, the difference of potential between the two electrodes gives an assessment of the composition of the sample. Potentiometry usually uses indicator electrodes made selectively sensitive to the ion of interest, such as fluoride in fluoride selective electrodes, so that the potential solely depends on the activity of this ion of interest. The most common potentiometric electrode is the glass-membrane electrode used in a pH meter.
Skoog, Douglas A.; Donald M. West; F. James Holler (1995-08-25). Fundamentals of Analytical Chemistry (7th ed.). Harcourt Brace College Publishers. ISBN 0-03-005938-0.
Kissinger, Peter; William R. Heineman (1996-01-23). Laboratory Techniques in Electroanalytical Chemistry, Second Edition, Revised and Expanded (2 ed.). CRC. ISBN 0-8247-9445-1.
Bard, Allen J.; Larry R. Faulkner (2000-12-18). Electrochemical Methods: Fundamentals and Applications (2 ed.). Wiley. ISBN 0-471-04372-9.
Zoski, Cynthia G. (2007-02-07). Handbook of Electrochemistry. Elsevier Science. ISBN 0-444-51958-0.
http://pubs.rsc.org/en/content/articlelanding/1947/an/an9477200094#!divAbstract
https://en.wikipedia.org/wiki/Electroanalytical_method
http://chemwiki.ucdavis.edu/Core/Analytical_Chemistry/Analytical_Chemistry_2.0/11_Electrochemical_Methods/11.2%3A_Potentiometric_Methods
Hoping this will be helpful,
Rafik
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