the diasteromeric adducts are (2S,3R,3R')-(-)-4-(4-Bromophenyl)-3-hydroxy-2-(1,7,7-trimethylbicyclo[2,2,1]heptan-2-on-3-yl)-4-oxobutanoic acid and (2R,3S,3R')-(+)-4-(4-Bromophenyl)-3-hydroxy-2-(1,7,7-trimethylbicyclo[2,2,1]heptan-2-on-3-yl)-4-oxobutanoic acid
Rafik Karaman
Dear Sameh,
Among the 4 diastereoisomers depicted in your Word file I expect that 2ii and 3ii will be the most reactive. Since the orientation of H and OH is similar in both 2ii and 3 ii I believe that their reactivity will be very close, or similar.
The principle here is to look at the orientation of H and OH; the best reactivity will be when both are in the anti conformation each to other.
Hoping this will be helpful,
Rafik
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