As pe my study C18 column will be good but what specific category of C18 should i prefer for these compounds i.e which specific C18 hplc collumn can detect all these compounds?
You may have a hard time detecting these compounds via HPLC using a UV detector. Toluene is probably the only one that will absorb strongly enough to be detected. I would suggest performing distillation separating by vapor temperature then taking H-NMR of the resulting fractions to determine their composition individually.