Thank you for your advice. I am going through IRC calculation, Mr Jamshidi suggests to add TD(calcfc,ts,noeigentest) along with level of theory and basis set but its not working . will you please to suggest the exact route section for optimization of transition state in excited state.
Thanks for your suggestion. I tried with Td(....) whatever you told but the job is terminating after a few second. Its showing " No analytic 2nd derivatives for this method."