For selective etching of germanium with regards to calcium fluoride (CaF2), I would suggest 'Billig's etch': K3[Fe(CN)6] (12 g) + KOH (8 g) + H2O (100 ml H2O).
I suggest conc. nitric acid for selective etching of magnesium fluoride (MgF2) with regards to calcium fluoride (CaF2).