suppose the activation energy determined from the Arrhenius behaviour of relaxation time of a ceramic material is around 0.08....................what does this signify?
it is about 8 kJ/mol, which is low. It would be good to know under what conditions did you measure this value. Is it determned from dieletcris loss tests? By time-temperature superposition? Or form AC conductivity data? The activation energy can be interpreted only if one has an idea about the physical mechanism behind it. If it is a local motion, usually there is some hopping or diffusion like motion behind it. It usually involves higher activation energy. if however, it is an elctronic process, the activation energy can be lower. So please specify the material and the conditions.
it is about 8 kJ/mol, which is low. It would be good to know under what conditions did you measure this value. Is it determned from dieletcris loss tests? By time-temperature superposition? Or form AC conductivity data? The activation energy can be interpreted only if one has an idea about the physical mechanism behind it. If it is a local motion, usually there is some hopping or diffusion like motion behind it. It usually involves higher activation energy. if however, it is an elctronic process, the activation energy can be lower. So please specify the material and the conditions.
actually the activation energy has been calculated from the impedance measurements (maximum frequency from imaginary Z* plot) for a ferroelectric material.
Dear Swetapadma, I am not an expert in inoragnic ferroelectric systems, therefore all I can do is to attach certain links. if you study them, you can get a general picture on dielectric phenomena in related systems and can find typical activation energy values measured by others. Comparing the experimental conditions and the materials composition you may find the clue how to interpret your own data.