What is the different between soot cluster and soot particle? In experiments, the smallest size of the observed nascent soot is regarded as soot particle or soot cluster?
Soot is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons.[1] It is more properly restricted to the product of the gas-phase combustion process[citation needed] but is commonly extended to include the residual pyrolysed fuel particles such as coal, cenospheres, charred wood, and petroleum coke that may become airborne during pyrolysis and that are more properly identified as cokes or chars.
Soot cluseters ARE clusters are evaluated on the basis of the measured angular patterns of the scattered light intensity. The major finding is that the kinetics of the coagulation process that yields to the formation of chain-like aggregates by soot primary particles (size 10 to 40 nm) can be described with a constant coagulation kernel βc,exp=2.37×10−9 cm3/s (coagulation constant τc≈0.28 ms). This result is in nice accord with the Smoluchowski coagulation equation in the free molecular regime, and, vice versa, it is in contrast with previous studies conducted by invasive (ex situ) techniques, which claimed the evidence in flames of coagulation rates much larger than the kinetic theory predictions.