PLA, PCL, starch, cellulose, chitosan and protein.
Please see the references below, you will find lots of interesting information:
JONG-WHAN RHIM, Natural Biopolymer-Based Nanocomposite Films for Packaging Applications. Critical Reviews in Food Science and Nutrition, 47:411–433 (2007). DOI: 10.1080/10408390600846366
Hernandez-Munoz, P. et al. 2003. Development and characterization of biodegradable films made from wheat gluten protein fractions. J. Agric. & Food Chem., 51:7647–7654.